After a bit of reading online and book reading (Learning Perl 2nd Edition), I came up with this;

#!/usr/bin/perl
# Revision 1 - 09-03-09 1530
# Countr Code list, stdin, perl
# SRC for codes: http://www.kropla.com/dialcode.htm

use Term::ANSIColor qw(:constants);
$Term::ANSIColor::AUTORESET = 1; #reset colors after each line

print GREEN "Please enter the country code you are trying to look up.\n";
$cc = <STDIN>;
chomp $cc;
if ($cc eq "1") {
print GREEN "United States of America or Canada.\n";
}
elsif ($cc eq "93") {
print RED "Afghanistan.\n"; }
elsif ($cc eq "355") {
print RED "Albania.\n"; }
elsif ($cc eq "213") {
print RED "Algeria.\n"; }
elsif ($cc eq "1684") {
print RED "American Samoa.\n"; }
elsif ($cc eq "376") {
print RED "Andorra.\n"; }
elsif ($cc eq "244") {
print RED "Angola.\n"; }
elsif ($cc eq "1268") {
print RED "Antigua.\n"; }
elsif ($cc eq "54") {
print RED "Argentina.\n"; }
elsif ($cc eq "374") {
print RED "Armenia.\n"; }
elsif ($cc eq "297") {
print RED "Aruba.\n"; }
elsif ($cc eq "247") {
print RED "Ascension.\n"; }
elsif ($cc eq "61") {
print RED "Australia.\n"; }
elsif ($cc eq "672") {
print RED "Australian Extrernal Territories.\n"; }
elsif ($cc eq "43") {
print RED "Austra.\n"; }
elsif ($cc eq "994") {
print RED "Azerbaijan.\n"; }
elsif ($cc eq "1242") {
print RED "Bahamas.\n"; }
elsif ($cc eq "973") {
print RED "Bahrain.\n"; }
elsif ($cc eq "880") {
print RED "Bangladesh.\n"; }
elsif ($cc eq "1246") {
print RED "Barbados.\n"; }
elsif ($cc eq "1268") {
print RED "Barbuda.\n"; }
elsif ($cc eq "375") {
print RED "Belarus.\n"; }
elsif ($cc eq "32") {
print RED "Belgium.\n"; }
elsif ($cc eq "501") {
print RED "Belize.\n"; }

Some of you may find this to be pretty elementary, but lets see what I can come up with in the next day or two. Essentially all this does is looks for a country that matches the code you put in. It does not include all countries, but I think I got the idea of elsif in perl.